Siconversionunits inviewofpresentacceptedpracticeinthistechnologicalarea,u. In many cases, problems with stress corrosion cracking scc can. The specificity of environments that will promote stress corrosion cracking is significant. Hydrochloric hcl acid corrosion is an acidic environment damage mechanism that can be a significant problem for operators of refining and chemical process units. Anybody aware of any ndt method that can be used to test for the presence of polythionic acid stress corrosion cracking in heatr pipes in a fired heater. Polythionic acid stress corrosion cracking ethylene. Stress assisted corrosion is a type of corrosion that can occur in metals due to elevated static tensile stress levels. For heaters with stainless steel tubes, an evaluation should be made to determine their susceptibility to internal and external pascc. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. Cracking of sensitized stainless steels inspectioneering. Standard practice for evaluating stresscorrosioncracking. Cracking was attributed to polythionic acid stress corrosion cracking. Stress corrosion cracking of sensitized austenitic. Stress corrosion is a form of galvanic corrosion, where stressed areas of the material.
Based on this analysis the leaks were caused by cracks that initiated on the id surface. Results reveal that the stress corrosion life decreases rapidly on increasing the concentration from 0. The purpose of this paper is to investigate stress corrosion cracking scc for 304, 316, and 321 stainless steels in petroleum. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Numerical modeling of stress corrosion cracking in polymers. Polythionic acid stress corrosion cracking deterioration. Substantial amounts of this acid are present in some oils. Polythionic acid stress corrosion cracking stainless steel. Typically, process unit construction materials are chosen to resist hydrochloric acid corrosion when the designers know where and how much hydrochloric acid will be present in the process. Presence of cr, carbon, exposure temperatures and presence of polythionic acids play an important role in stress corrosion cracking.
The sensitization curves for solutionannealed wrought stainless steels, which had been held for varying times at temperatures. The mechanism of stress corrosion cracking scc involves a very complicated sequence of corrosion and fracture. C, and type 316 stainless is sometimes required as a constructional material. Corrosion causes a material to age in a particular manner and speed, and stress causes it to fracture after a certain period of time, says bilge yildiz, associate professor of nuclear science and. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. Corrosion issues in black liquor gasifiers james r. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. This study investigates the deformation behaviour of a newly developed highstrength lowalloy mg alloy. Ctlpolythionic stress corrosion cracking of stainless. For the purposes of this document, corrosion includes general and localized corrosion mechanisms, as well as environmental cracking mechanisms including, but not limited to, stress corrosion cracking scc, sulfide stress cracking.
Refer also to nace rp0170, protection of austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking during shutdown of refinery equipment. However, any engineer hoping to take advantage of these benefits must consider the possibility of stress corroslon cracking. Stresscorrosion cracking of a monel 400 tube springerlink. Access is restricted to employees of subscribing companies.
It is important to realize that not all corrosive environments promote the formation of stress corrosion cracks. Naphthenic acid, when present in oils, can be quite corrosive at 221 to 399. In stabilized grades of austenitic steel, titaniumniobium are added which have stronger affinity to form carbides than chromium, thus protecting corrosion resistance. Scc occurs as a result of a combination between corrosion and tensile stress. Metallurgy solution to prevent polythionic acid stress. Polythionic acid is formed in the presence of sulfur, moisture and oxygen. Polythionic acid stress corrosion cracking pascc is an affliction of many refineries processing sulfur containing feedstocks, and since that is the norm these days, most refiners reduce their susceptibility to pascc by selecting resistant alloys orby neutralizing exposed surfaces during shutdowns. When waste heat recovery boilers were first introduced it was considered that dew point corrosion would be the most important problem to be overcome. Comparative stress corrosion cracking and general corrosion resistance of annealed and hardened 440c stainless steelnew techniques in stress corrosion testing m. Why does chloride stress corrosion cracking and pascc only. Stress corrosion cracking industrial metallurgists.
Are there any methods that can be used to give a 100% picture of the status of the pipes whilst they are mounted in the heater. Polythionic acid stress corrosion cracking of 310 stainless steel. Stress corrosion cracking resistance ubend samples in boiling chloride solutions 14 threshold temperatures for chloride scc in 3% sodium chloride 14 maximum suggested temperatures for heat resistant alloys 14. Polythionic acid stress corrosion cracking during shutdown of refinery.
Chloride stress corrosion cracking polythionic acid stress corrosion cracking from mechanical 1011 at albany state university. Polythionic acid promotes intergranular scc in sensitised austenitic grades of stainless steel. Specifically, it is a stress attack directed at locations where applied or residual stresses are imparted to the metal. Effect of polythionic acid concentration on stress. Stress corrosion cracking scc of hydrogenated austenitic stainless steels was investigated in polythionic acid solution. This alloy is known for both its durability to fight intergranular corrosion and its structural integrity that can withstand harsh conditions of the refining processes. Protection of austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking during shutdown of refinery equipment. Protection of austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking during a shutdown of refinery equipment. If the cracking has been correctly diagnosed as chloride stress corrosion cracking, and the problem is confined to small drain, flush fittings, etc. If you did not receive an email with instruction on how to set up your individual access, please contact your companys site access coordinator from the list below.
Chloride stress corrosion cracking polythionic acid stress. For less severe conditions 5 % cr steel is satisfactory. Nov, 1990 the alloy is, however, susceptible to intergranular polythionic acid stress corrosion cracking. Polythionic acid may be present in petrochemical environments. What causes stress corrosion cracking in pipelines. Intergranular and transgranular stress corrosion cracking of the aisi 316l stainless steel at polythionic acid. Effects of sensitization and service fluid chemistry on. Both austenitic and straight chromium grades of stainless steels can be attacked by polythionic acid. In recent years, however, an unforeseen corrosion problem has emerged. Polythionic acid stress corrosion cracking pascc is a type of intergranular stress corrosion that affects sensitized stainless steels in refineries processing. Polythionic acid stress corrosion cracking in heater pipes. Polythionic acids form from sulfide scales exposed to oxygen and water in the stainless steel that are sensitized which can occur in most stainlesssteel tube materials after exposures to temperatures in excess of 700f to 1500f 371c to 815c during manufacturing, fabrication or in service. The most common fluid that causes inter granular stress corrosion cracking igscc in petrochemical plants and refineries is polythionic acid. Polythionic stress corrosion cracking of stainless steel tube.
Hydrotreating is a staple process found in nearly every refinery. Stress corrosion cracking scc is a fracture process that involves the combined and simultaneous action of a tensile stress and a corrosive environment. Stress corrosion cracking scc is a type of environmentallyassisted cracking eac, or the formation of cracks caused by various factors combined with the environment surrounding the pipeline. Sulfur can come from feed stock, additives or fuels. A major problem is stress corrosion cracking, which combines chemical attack in the form of corrosion with stress from mechanical loads.
Further progress is then a process alternating between corrosion. Polythionic acid stress corrosion cracking of type 310 stainless steel. The pipeline was used to carry a stream of gaseous hydrocarbons containing hydrochloric acid hcl into a reaction tower. The process removes undesirable feed contaminants, such as sulfur, nitrogen and metals, and saturates olefins andor aromatics to produce highquality products. The cracks are intergranular and narrow with no significant branching.
Pascc stands for polythionic acid stress corrosion cracking oil refining. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. This damage mechanism primarily affects standard and high carbon stainless steels, but low carbon and chemically stabilized stainless steels may also be vulnerable under certain conditions. This type of failure is known as stress corrosion cracking, often abbreviated to scc. All of the cracks observed were found underneath the coke deposits. Examples of polythionic acid scc pascc in a sensitized austenitic stainless steel and caustic scc in carbon steel equipment are presented. Metallurgy solution to prevent polythionic acid stress corrosion cracking in hydroprocessing. The most common fluid causing intergranular corrosion in hydrocarbon plants is polythionic acid. Polythionic acid stress corrosion cracking pascc is a type of intergranular stress corrosion that affects sensitized stainless steels in refineries processing feedstocks containing sulphur. This damage mechanism primarily affects standard and high carbon stainless steels, but low carbon and chemically stabilized stainless steels may also be. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments.
Numerical modeling of stress corrosion cracking in polymers a thesis submitted to the faculty of the graduate school of the university of minnesota by hanxiao ge in partial fulfillment of the requirements for the degreee of doctor of philosophy professor, susan c. In the presence of sulfide corrosion products, such conditions are met during shutdown, when moisture originates from general humidity, washing or steam out and oxygen as air enters the unit upon opening to atmosphere. Stress corrosion cracking facts and how to reduce the. Polythionic acid stress corrosion cracking stainless. Low temperature stress corrosion cracking of sensitized stainless steel, promoted by aqueous solutions of polythionates sxo62. This standard is directed toward preventing stress corrosion cracking scc caused by polythionic acid pta that can be formed by reaction of oxygen and water with sulfide corrosion products i. Scc in pipelines is further characterized as high ph scc or nearneutral ph scc. Mechanical engineering assignment help, polythionic acid stress corrosion cracking, in naphtha hydrotreating unit, does feedeffluent heat exchangers require passivation to avoid polythionic acid stress corrosion cracking. Precautions to avoid polythionic acid stress corrosion. Corrosion behavior of austenitic stainless steel in sulphuric. Polythionic acid stress corrosion cracking, mechanical. The stress can be externally applied or it can be an internal residual stress.
Stress corrosion cracking issues in syngas plants that may be. How is polythionic acid stress corrosion cracking oil refining abbreviated. What are the industrial practices being followed in. Danford marshall space flight center, marshall space flight center, alabama national aeronautics and space administration. Alloy for resistance to polythionic acid stress corrosion cracking for. Subsequently, this particular form of intergranular scc was called polythionic acid stress corrosion cracking pascc. Stress corrosion cracking scc is an interaction between tensile stress and corrosion, whlch results in. Intergranular cracking tendencies of fourteen stainless steels and two highnickel alloys have been evaluated by exposing numerous specimens to polythionic acid and standard acid copper sulfate solutions. Nitrate stress corrosion cracking in waste heat recovery. These characteristics are consistent with stress corrosion cracking due to polythionic acids. Current studies on the subject of stress corrosion cracking indicate a pressing need for basic research to elucidate the chemical and physical processes that are pertinent to the process of stress corrosion cracking. Stress corrosion cracking will usually cause the material to fail in a brittle manner, which can have grave consequences as there is usually little or no warning before the failure occurs. Stress corrosion cracking susceptibility of stainless. The test may not be relevant to stresscorrosion cracking in polythionic acid or caustic environments.
This phenomenon is usually an internal problem, occurring on the processexposed side of a piping run, vessel shell, exchanger bundle, heater tube. Corrosion and stress corrosion cracking in coal liquefaction. Stresscorrosion cracking, materials performance and. The austenitic stainless steel tubes in these services can be susceptible to polythionic acid stress corrosion cracking. Polythionic acid corrosion in refinery hydroprocessors. Effects of sensitization and service fluid chemistry on polythionic acid stress corrosion cracking of 188 stainless steels. Analysis of the cracking showed the mechanism was chloride stress corrosion with. The problem of stress corrosion cracking scc, which causes sudden failure of metals and other materials subjected to stress in corrosive environments, has a significant impact on a number of sectors including the oil and gas industries and nuclear power production. Once the metal is sensitized, sulfide scale on the metal can react with moisture and air, typically during shutdowns, to form polythionic acid. However, some significant materials problems should be solved to enable economic and reliable scaleup to commercial levels of production.
If moisture is present in an alkaline environment it may absorb ammonia and such solutions, in conjunction with residual stress, can initiate stress corrosion cracking. Cracking caused by polythionic acid can occur in the annealed condition or after long term exposure at simulated operating temperatures up to about 649 c. Alloy 321 is a durable stainless steel plate stabilized with titanium, which helps it withstand the threat of stress cracking caused by sulfides found in polythionic acid services. The temperature of the column in the region of the cracking is approximately 70c 158f.
Stress corrosion tests using ubend specimens were carried out in samans solutions containing polythionic acid concentrations from 0. It has been shown that, for some materials, fine pitting is needed to start the activity. There are specific stresscracking agents for brasses, these are usually ammonia or its derivatives. Alloy for resistance to polythionic acid stress corrosion. Scc occurs when the tensile stress and a specific environment are able to cause failure by their combined action, but are insufficient to cause failure by either one acting alone. A web site analysing and providing results on stainless steel tube cracked by polythionic stress corrosion. Then sulfide scales react with oxygen and polythionic acid is produced, leading to cracking in the presence of residual internal stresses at the sensitized material of the reactor tube. Polythionic acid is generated in petrochemical process. The tower provided a caustic solution naoh to remove hcl from the stream, before the latter was directed to a burner. Chemical studies of polythionic acid stresscorrosion cracking. Pdf polythionic acid corrosion in refinery hydroprocessors. This new second edition serves as a goto reference on the complex subject of stress corrosion cracking scc, offering information to help metallurgists, materials scientists, and designers determine whether scc will be an issue for their design or application. Samans, stress corrosion cracking susceptibility of stainless steels and nickelbase alloys in polythionic acids and acid copper sulfate solution, corrosion.
Failures due to inadequate materials performance have been reported in many plant areas. Note that the ph here refers to the environment on the pipe surface at the crack location, not the ph of the soil itself. Pdf stress corrosion cracking damages researchgate. Corrosion is related to the susceptibility of the material to the environment, while stresses may be residual, external. The cracking was found when rust stainingleaks were observed. Pascc polythionic acid stress corrosion cracking oil. The item was exposed to sulfur containing natural gas in a continuous flare.
Corematerials polythionic stress corrosion cracking of. Stress corrosion cracking scc is the simultaneous action of a tensile stress and an aggressive environment on an alloy system to produce a brittle fracture in a normally ductile material at stress levels far below engineering design limits. It is especially important to avoid any mechanical tensile stress concentration, which will occur at sharp edges and notches. Polythionic acid stress corrosion cracking free download as word doc. However, to avoid scc in austenitic ss steels, exposure to conducive environment polythionic acid formation in presence of oxygenwaterchlorides along with metal sulfidesh2s to be reduced by adopting. A bent nicu monel 400 alloy tube, which operated as part of a pipeline in a petrochemical distillery installation, failed by throughthickness cracking. The resistance to stress corrosion cracking is very dependent on metal susceptibility to ignition processes. If deemed necessary, specific steps should be taken to prevent cracking during downtime. Heat treatment method for reducing polythionic acid stress. Stress corrosion cracking issues in syngas plants that may. Polythionic acid stress corrosion cracking pascc in stainless steel is a downtime phenomenon. Abstractlow temperature stress corrosion cracking of sensitized stainless steel, promoted by aqueous solutions of polythionates sxo, and related sulfur compounds. Severe stress corrosion cracking was observed in the csbp ltd, western australia 304l unlagged stainless steel absorber column of a nitric acid plant after 15 years of plant operation. Pascc is defined as polythionic acid stress corrosion cracking oil refining somewhat frequently.
864 1254 1583 608 213 1404 1299 1282 1526 1524 855 1347 250 94 493 1317 1187 1171 572 173 344 654 638 1373 393 1364 346 1340 167 802 88 1106 1236 401